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Carboranylphosphites as new ligands for Rh-catalyzed asymmetric hydrogenation

โœ Scribed by S. E. Lyubimov; A. S. Safronov; A. A. Tyutyunov; V. N. Kalinin; E. E. Said-Galiev; A. R. Khokhlov; P. V. Petrovskii; P. M. Valetskii; V. A. Davankov

Book ID
106520790
Publisher
Springer
Year
2008
Tongue
English
Weight
305 KB
Volume
57
Category
Article
ISSN
1573-9171

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Aminophosphine phosphinites of propranol
Aminophosphine phosphinites of propranolol analogues as ligands for Rh-catalyzed asymmetric hydrogenation
โœ H.W. Krause; U. Schmidt; S. Taudien; B. Costisella; M. Michalik ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 936 KB

Chiral aminophosphine phosphinites of a series of propranolol derivatives have been prepared and their Rh chelates tested in the asymmetric hydrogenation of standard amino acid precursors. In order to optimize the stereoselectivity of the catalyst the Nsubstituents of the starting 1,2-amino alcohols