Carbonyl(pentaphosphacyclopentadienyl)-Übergangsmetallkomplexe (M = Cr, Mo, W, Mn) durch gezielte Synthese mit cyclo-P

Carbonyl(pentaphosphacyclopentadienyl)-T

Carbonyl(pentaphosphacyclopentadienyl)-Transition Metal Complexes (M Cr, Mo, W, Mn) through Directed Syntheses with cyclo-P

✍ Prof. Dr. Marianne Baudler; Dipl.-Chem. Thomas Etzbach 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 369 KB

phosphorus (3Jc-p = 6.2 and 5.7 Hz, respectively) indicating an antiperiplanar conformation of the C-S-C-P fragment and hence the prevailing equatorial position of the triphenylphosphonium group in solution. The y-effect values (+ 0.135 and -0.26 for 3 and 4, respectively) are also in accord with th