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Carbonyliron-Assisted Cycloaddition of a 1,3-Diene to a CC Double Bond: Synthesis of an Anthracyclinone Precursor

โœ Scribed by Philippe Vioget; Prof. Dr. Pierre Vogel; Prof. Dr. Raymond Roulet


Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
240 KB
Volume
21
Category
Article
ISSN
0044-8249

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A simple and efficient method for the synthesis of novel spiropyrrolidines has been accomplished by regioselective 1,3-dipolar cycloaddition reactions of an azomethine ylide generated by thermalring opening of cis-1-cyclohexyl-2-phenyl-3-benzoyl aziridine with various (E)-3-arylidene-4-chromanones.