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Carbonylative Approaches to α,β-Unsaturated Acyl Radicals and α-Ketenyl Radicals. Their Structure and Applications in Synthesis

✍ Scribed by Ilhyong Ryu; Yoshitaka Uenoyama; Hiroshi Matsubara


Publisher
John Wiley and Sons
Year
2007
Weight
12 KB
Volume
38
Category
Article
ISSN
0931-7597

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✍ Dipl.-Chem. Karola Rück; Prof. Dr. Horst Kunz 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 351 KB 👁 1 views

and treated with lBuCl (1.18 g, 12.8 mmol) directly after filtration. The mixture was stirred at room temperature for 12 h before the orange solution was evaporated to dryness. Recrystallization of the residue from toluene (ca. 30 mL) affords a yellow crystalline powder (2.50 g, 40%). which decompos