## Hydroformylation of Olefins in the Presence of Rhodium Catalysts Immobilized on Polymeric Pyrrolidinopyridines. -The hydroformylation of olefins in the presence of catalytic systems based on RhCl3 and polymeric pyrrolidinopyridine is studied. This thermostable catalyst system is shown to be mo
Carbonylation of methyl acetate in the presence of rhodium catalysts based on pyrrolidinopyridine polymers
✍ Scribed by G. V. Terekhova; N. V. Kolesnichenko; A. E. Batov; E. D. Alieva; N. I. Trukhmanova; E. V. Slivinskii; O. Yu. Pesin; N. A. Platé
- Publisher
- Springer
- Year
- 1999
- Tongue
- English
- Weight
- 152 KB
- Volume
- 48
- Category
- Article
- ISSN
- 1573-9171
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📜 SIMILAR VOLUMES
In presence of the homogenous Rh/Cr/I catalyst system methyl formate can be isomerized to acetic acid under CO-pressure with high conversion rates and excellent selectivity. This catalyst system has never been applied before for this reaction.
## Abstract The homogeneous catalyst CpTiCl~3~‐MAO is able to produce a random copolymer of 4‐methyl‐1,3‐pentadiene with ethylene. ^13^C NMR analysis of the copolymers shows that after insertion of ethylene units, the next 4‐ymethyl‐1,3‐pentadiene unit can be inserted in either 1,2 or 1,4 arrangeme