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Carbonylation of alkenyl-complexes of ruthenium. The formation of complexes containing, alkene or acyl ligands, and the reaction of the acyl complexes with methanol

✍ Scribed by M.Rosario Torres; Aurea Perales; Hassane Loumrhari; Josep Ros


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
277 KB
Volume
384
Category
Article
ISSN
0022-328X

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Square-Planar Carbonylchlororhodium(I) C
✍ Sylvain Burger; Bruno Therrien; Georg SΓΌss-Fink πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 German βš– 113 KB

## Abstract The rhodium(I) complexes __trans__‐[Rh(diphos)(CO)Cl] **7** (diphos=pbpb), **8** (diphos=nbpb), and **9** (diphos=cbpb) were synthesized (__Schemeβ€…4__) and used as catalysts for the carbonylation of MeOH to AcOH (__Schemeβ€…1__). The __trans__ coordination imposed by the rigid C‐spacer fr