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Carbonylation of 2-bornenyl(methyl)zirconocene

✍ Scribed by Gerhard Erker; Ralf Noe; Markus Albrecht; Arnold L. Rheingold

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
784 KB
Volume
450
Category
Article
ISSN
0022-328X

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✍ Gilbert Agnel; Zbyslaw Owczarczyk; Ei-ichi Negishi 📂 Article 📅 1992 🏛 Elsevier Science 🌐 French ⚖ 226 KB

## summaly: Allylically methyl-substituted 1,6\_heptenynes, such as 3-methyl-1,6-octenyne, can be diastereoselectively converted to the corresponding bicyclic ketones, such as (SR,6S)-2,6-dimethylbicyclo[3.3.0]oct-l-en-3one readily convertible to (+)-iridomynnecin, the observed diastereomeric exce