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Carbonyl(1-methyl-η5-cyclopentadienyl)bis(triphenylphosphine)manganese dichloromethane solvate

✍ Scribed by Rheingold, A. L. ;White, C. B. ;Haggerty, B. S. ;Terry, M. R. ;Geoffroy, G. L.

Book ID
114509359
Publisher
International Union of Crystallography
Year
1992
Tongue
English
Weight
315 KB
Volume
48
Category
Article
ISSN
0108-2701

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📜 SIMILAR VOLUMES

μ-Carbonyl-1:2κ2C-carbonyl-1κC-(1η5-cycl
μ-Carbonyl-1:2κ2C-carbonyl-1κC-(1η5-cyclopentadienyl)(μ-phenylvinylidene)bis(triphenylphosphine-2κP)manganeseplatinum(Mn—Pt)
✍ Vasiliev, Alexander D. ;Antonova, Alla B. ;Chudin, Oleg S. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 1002 KB

The title compound, [MnPt(C 5 H 5 )(C 8 H 6 )(C 18 H 15 P) 2 (CO) 2 ], is a dinuclear heterometallic Mn-Pt(-C CHPh) complex obtained as a product of the addition of [Pt(PPh 3 )] 2 to ( 5 -C 5 H 5 )(CO) 2 Mn C CHPh. The two metal atoms are bridged by the -phenylvinylidene ligand and semibridged by a