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Carbonyl intra-exchange in hexa- and hepta-rhodium carbonyl clusters

✍ Scribed by Heaton, Brian T.; Towl, Anthony D. C.; Chini, Paolo; Fumagalli, Alessandro; McCaffrey, David J. A.; Martinengo, Secondo


Book ID
119938831
Publisher
The Royal Society of Chemistry
Year
1975
Tongue
English
Weight
228 KB
Volume
13
Category
Article
ISSN
0022-4936

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Dynamic 13C NMR studies of ligand exchan
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The dynamic CO exchange of the monovalent metal carbonyl cations [Ag( 13 CO)] + , [Au( 13 CO) 2 ] + -Au( 13 CO) SO 3 F and [Rh( 12 CO) 4-x ( 13 CO) x ] + (x 1) in superacidic solutions was studied by variable-temperature 13 C NMR methods. The exchange rates are strongly dependent on the acidity of t