Changes of composition, structure, and contents of some functional groups, of oils from petroleum binders, in relation to temperature of carbonization from about 710 K to 1200 K have been investigated. Oils from carbonization of petroleum binders are of hydrocarbon type, and their elemental composit
Carbonization of petroleum binders. 1. Characteristics of solid products
โ Scribed by Jadwiga Wieckowska; Jan Chmielewski
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 594 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0016-2361
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โฆ Synopsis
Solid products of carbonization of residues (i.e. cokes) of vacuum distillation of crude oil, asphalt, and pitch have been studied. The objective was to determine the changes of composition and structure of cokes in relation to temperature. Investigations of elemental composition, functional group content, microscopic analysis, and X-ray diffraction of the products showed that with increasing temperature of carbonization, the degree of structure ordering, the dimensions of the pores, and the intensity of optical anisotropy of the cokes increases, as do the carbon, sulphur, and nitrogen contents; however, volatile matter, hydrogen, and functional-group contents in the cokes decrease.
๐ SIMILAR VOLUMES
The early stage of carbonization of petroleum pitches has been studied by in-situ, hightemperature 'H-NMR and ESR techniques. Well-resolved 'H-NMR spectra were found to provide cletailed information about the mesophase formation in the course of pyrolysis. The process of mesophase generation during