The aluminum chloride catalyzed carbonization of heterocyclic nitrogen compounds such as carbazole, phenazine, and acridine was studied from the viewpoint of the kinetics and the structure of intermediates, in order to elucidate how the similar nitrogen compounds were carbonized to cokes of differen
Carbonization of aromatic hydrocarbon—VII: The role of active carbonizing species in the catalytic carbonization of pyrene
✍ Scribed by Isao Mochida; Keishi Otsuka; Keiko Maeda; Kenjiro Takeshita
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 725 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0008-6223
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✦ Synopsis
Carbonization
of pyrene with naphthalene was studied in the presence of aluminum chloride in order to reveal the effects of active species on the formation of the needle coke. A certain amount of naphthalene was found to help the formation of a needle coke from pyrene with aluminum chloride of 0.1 mole ratio which produced a mosaic coke without naphthalene. Roles of naphthalene are discussed from the aspects of its reactivity in the carbonization reaction.
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