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Carbonium ions. XXIII. Chain elongation in the rearrangement of 2,3-dimethyl-4-penten-2-ol to 2-methyl-3-hexen-2-yl cations

โœ Scribed by Deno, N. C.; Lastomirsky, Robert R.


Book ID
127002570
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
153 KB
Volume
40
Category
Article
ISSN
0022-3263

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Based on the surprising observation of an intense C4H9+ (m/z 57) peak in the electron impact mass spectrum, the fragmentation of 1,1,2,2,3,3-hexamethylindan (2) was studied by mass-analysed ion kinetic energy spectrometry of its deuterium-labelled analogues. While methyl loss from ions [ 21 +' occur