Carboncarbon bond formation on solid support. Application of the classical Julia–Lythgoe olefination

✍ Scribed by Jo N.P. D'herde; Pierre J. De Clercq

• Book ID: 104254235
• Publisher: Elsevier Science
• Year: 2003
• Tongue: French
• Weight: 104 KB
• Volume: 44
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(03)01637-x

✦ Synopsis

Reductive elimination of b-benzoyloxysulfones, obtained via solid-phase organic synthesis, with samarium diiodide in the presence of DMPU favors the formation of trans-alkenes.