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Carbon–carbon bond formation between secondary alcohols and aldehydes under ruthenium-catalyzed redox shuttle

✍ Scribed by Chan Sik Cho; Bok Tae Kim; Nam Sik Yoon

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 91 KB
Volume: 25
Category: Article
ISSN: 0268-2605
DOI: 10.1002/aoc.1829

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✦ Synopsis

Abstract

Secondary alcohols are coupled with aldehydes in dioxane in the presence of a catalytic amount of a ruthenium catalyst along with KOH to give coupled ketones or coupled secondary alcohols depending on the molar ratio of secondary alcohols to aldehydes and the presence (or absence) of a sacrificial hydrogen acceptor. Copyright © 2011 John Wiley & Sons, Ltd.

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