## Abstract At temperatures of 356β425Β°C and pressures of 15β60 Torr, cyclopropylamine reacts to give an equimolar mixture of ammonia and Nβpropylidenecyclopropylamine as the initial product. The reaction is first order, homogeneous, and unaffected by the presence of radical inhibitors, and thus pr
Carbonate pyrolysis. Part 5. The gas-phase pyrolysis of some unsymmetrical monothiolcarbonates and a rationalisation of the rates of some related reactions
β Scribed by Al-Awadi, Nouria; Bigley, David B.
- Book ID
- 120644406
- Publisher
- Royal Society of Chemistry
- Year
- 1979
- Tongue
- English
- Weight
- 527 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1472-779X
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The reactions of dimethylsilylene, SiMez, generated by laser flash photolysis from pentamethyldisilane and octamethyltrisilane, and detected via its 457.9 nm absorption, have been investigated with a number of oxygen containing molecules, including oxygen itself, carbon monoxide, water, alcohols, an
## Abstract In the gas phase, __cis__,__trans__β1,5βcyclooctadiene (\documentclass{article}\pagestyle{empty}\begin{document}$ {\mathop 1\limits\_\sim} $\end{document}) undergoes a unimolecular rearrangement to __cis__,__cis__β1,5βcyclooctadiene (\documentclass{article}\pagestyle{empty}\begin{docume