The electrochemical behaviour of PbO, at the solid state at a carbon paste electrode is studied. Several experiments with Pb,O, and PbO are also carried out in order to elucidate the electrochemical transformation of PbO,, occuring within +0.65 to -1.5 (see) range, into the carbon paste electrode wi
Carbon paste electrodes with electrolytic binder: Influence of the preparation method
✍ Scribed by M. T. Ramírez; M. E. Palomar; I. González; A. Rojas-Hernández
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 463 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1040-0397
No coin nor oath required. For personal study only.
✦ Synopsis
A method for the construction of carb'on paste electrodes (CPE) is described. Here ferrocene is used as the insoluble electroactive species, graphite powder as conductor and sulfuric acid as binder. The CPE thus prepared prevents ferrocenium ions from diffusing towards the bulk solutions. Voltammetric, chronolpotentiometric and chronoamperometric experiments performed with these CPEs show that the different preparation methods yield different electrochemical parameters for the ferrocene-ferrocenium system.
📜 SIMILAR VOLUMES
## Abstrati -We have used the carbon paste electrode to study some rhodium compounds in various media. The oxidation of Rh(0) led to the formation of two different types of the Rh(III) complex in 6M HCl, while the reduction of RhCl. 3H,O was found to take place at about the same potential that the
The carbon paste electrode has been used for studying the stoichiometry of the electrochemical reduction of Pt(IV) and Pt(II) and of the electrochemical oxidation of Pt(I1) and platinum black in acidic media. The electrochemical reduction of PtO, in 2 M H,SO, and in HCl(2 M and 6 M) was also reporte
Abatmct-Electroanalytical behaviour of Nh ScO, at solid state as well as in solution with a carbon paste eMrode is studied by voltammetric techniques. We have shown that Se(+IV) is reduced to grcy Se and after to w-11) and red Se, as well as that Na#e04 is not electroactive with this electrode. Fina