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Carbon monoxide exchange in 1,2-dimethyl-1,3,2-diazaphosphenium tetracarbonyliron cation

✍ Scribed by Bennett, Dennis W.; Parry, Robert W.

Book ID
127113463
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
422 KB
Volume
101
Category
Article
ISSN
0002-7863

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## Abstract Stereoisomeric ion pairs are implicated as intermediates in the solvolysis of __cis__ and __trans__‐1‐chloro‐1,2‐dimethylcyclohexane, __cis__‐**4** and __trans__‐**4**, respectively. This follows from the rates and products of these stereoisomeric tertiary chlorides in 80% ethanol and 5