Carbon monoxide activation by poly(1-pyrazolyl)boratoiridium complexes
✍ Scribed by Maria J. Fernandez; Maria J. Rodriguez; Luis A. Oro
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 386 KB
- Volume
- 438
- Category
- Article
- ISSN
- 0022-328X
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📜 SIMILAR VOLUMES
The activation of carbon-carbon s bonds under the influence of transition metals remains a fundamental challenge in organometallic chemistry. [1] Methylenecyclopropane and its derivatives were among the first substrates for which involvement of CÀC single bonds in transition-metal-catalyzed cycloadd
## Abstract Seven Pd‐complexes with optically active bis[dihydroxazole]‐type ligands promote asymmetric alternating copolymerization of 7‐methylenebicyclo[4.1.0]heptane with CO, which produces an optically active polyketone, [C(CH~2~)COC~6~H~10~]~__n__~. The reaction under increased CO pressur