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Carbon isotope effect studies in the mechanism of reactions of alkynes with formic acid

✍ Scribed by M. Zieliński; A. Zielińska; H. Papiernik-Zielińska; G. Czarnota; G. Kasprzyk; J. A. McKenzie; H. Paul; S. Bernasconi

Publisher
Springer
Year
1997
Tongue
English
Weight
468 KB
Volume
223
Category
Article
ISSN
1588-2780

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## Abstract The use of kinetic isotope effects (KIEs) for the short‐lived radionuclides ^11^C and ^18^F in the study of reaction mechanisms is described using some examples. Leaving group fluorine KIEs (__k__^18^/__k__^19^) have been utilized to determine the rate‐limiting step for nucleophilic aro