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Carbon dioxide effect on palladium-catalyzed sequential reactions with carbon monoxide, acetylenic compounds and water

✍ Scribed by G.P. Chiusoli; M. Costa; L. Cucchia; B. Gabriele; G. Salerno; L. Veltri


Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
147 KB
Volume
204-205
Category
Article
ISSN
1381-1169

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Enol acetates derived from saturated ketones are converted to a,&unsaturated ketones by heating with ally1 methyl carbonate in MeCN by bimetallic catalysis of palladiumphosphine complex and tin methoxide. Conversion of saturated ketones to corresponding a,&unsaturated ketones is an important synthet