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Carbon dioxide and monoxide used to make biopolymers

Publisher: Elsevier Science
Year: 2008
Weight: 47 KB
Volume: 2008
Category: Article
ISSN: 1351-4180
DOI: 10.1016/s1351-4180(08)70375-1

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## Abstract The Pd‐catalyzed addition of carbon monoxide and carbon tetrachloride to 1‐octene gave coadduct [alkyl 2‐(2, 2, 2‐trichloroethyl)octanoate] as the major product in supercritical carbon dioxide by using pyridine as the base. It was found that the selectivity and the yield of coadduct wer