Carbon-carbon bond fragmentation through oxidative electrolysis of carboxylic acids and its application to the synthesis of malyngolide
✍ Scribed by Wuts, Peter G. M.; Cheng, Minn Chang
- Book ID
- 127098846
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 600 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
The bicyclic ethers obtained by the oxymercuration-demercuration reaction of linalool was found to be formed in the demercurotion step. The facile C-C bond formation is due to the proximity of Hg and the vinyl group in the organomercurial intermediate. Applying this process to epimanool a biomimetic
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract The asymmetric synthesis of α‐substituted α‐amino acids and propargylamines is described. As chiral auxiliary we used (__S__)‐(–)‐1‐dimethoxymethyl‐2‐methoxymethylpyrrolidine (SDMP, **1**). Treatment of the amino acids or amines with SDMP **1** afforded the corresponding amidines **C**,