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Carbon-carbon bond formation at a diiron center. 5. Versatile action of phosphines on Fe2(CO)6(.mu.-COEt)(.mu.-CRCR'H) complexes (R = R' = Ph, H)

โœ Scribed by Yanez, Ramon; Ros, Joseph; Dahan, Francoise; Mathieu, Rene

Book ID
127025799
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
652 KB
Volume
9
Category
Article
ISSN
0276-7333

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Carbon-carbon bond formation at a dinucl
Carbon-carbon bond formation at a dinuclear iron center. 4. Synthesis of [Fe2(CO)6(.mu.-C(OR)H)(.mu.-CR'=CR'H)]- anions (R = Me, Et; R' = Ph, H) and the subsequent formation by protonation of the bridging vinylcarbene ligands >CHCR'=CR'H or >CR'CH=CR'H, depending on the reaction conditions
โœ Yanez, Ramon; Ros, Joseph; Solans, Xavier; Font-Altaba, Manuel; Mathieu, R. ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 615 KB