Carbon-carbon bond cleavage during silane reductions of the dimer of 2-phenylisophosphindole oxide
โ Scribed by Quin, Louis D.; Bernhardt, F. Christian
- Book ID
- 127193221
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 389 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Benzyltrirrethylsilanes react with cerium(IV) ammonium nitrate in AcOH to give products -of C-Si cleavage (benzyl nitrate and acetate), under very mild conditions and in quantitative yields. The reaction rate is very sensitive to the nature of the ring substituents (y= -5.4), which clearly suggests
The reaction of dispiro[cyclopropane-l,l'-indan-3',1"-cyclopropane]-2'-one (1) under Wolff-Kishner conditions gives spiro[cyclopropane-l,l'-indan] (2) in which the ketone has been reduced and two bonds of one cyclopropane ring have been cleaved. The Wolff-Kishner reaction is a classic method for