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Carbon based catalytic briquettes for the reduction of NO: Catalyst scale-up

✍ Scribed by A. Boyano; M.E. Gálvez; R. Moliner; M.J. Lázaro


Book ID
104009806
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
802 KB
Volume
137
Category
Article
ISSN
0920-5861

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✦ Synopsis


Exhaust gasses from small and medium stationary sources contain NO x that will be regulated by new European legislation in the coming years. Among all the processes the SCR-NH 3 seems to be the more promising one. However, the application of commercial catalysts to these new facilities presents some drawbacks such as the high and narrow operation temperature, its low withdraw to SO 2 or its high cost production.

In order to improve this technology, in previous works, carbon-supported catalytic briquettes have shown a good kinetic performance under the above commented conditions. In this study, other aspects such as thermal stability, long-term performance, spatial velocity influence and mechanical resistance were evaluated. Finally, a simple economic assessment was carried out providing a three times lower cost production than commercial catalysts. From all the data collected, there are some evidences that these catalyst briquettes will have a good performance in small and medium facilities, being an interesting alternative to commercial ones.


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Low-cost carbon-based briquettes for the
✍ M.E. Gálvez; A. Boyano; R. Moliner; M.J. Lázaro 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 866 KB

Catalytic briquettes were prepared using a low-rank coal as carbon precursor and vanadium compounds, i.e. V 2 O 5 and petroleum coke ash (PCA), as the source of the active phase. The catalytic briquettes presented herein offer a feasible low-cost possibility for flue gas cleaning in medium and small