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Carbon-13 spin-lattice relaxation times and nuclear overhauser enhancements in some simple fluorocarbons

✍ Scribed by Geoffrey E. Hawkes; Raymond J. Abraham

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
351 KB
Volume
6
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Carbon‐13 spin‐lattice relaxation times (T~1~) and ^13^C‐{^19^F} nuclear Overhauser enhancement (NOE) factors have been measured for some simple fluorocarbons by pulse‐Fourier transform methods—‘progressive saturation’ and ‘dynamic Overhauser enhancement’. The NOE factors are shown to be large for ^13^C with directly bonded fluorines, and the values for T~1~ and the NOE factors are similar to those obtained elsewhere on the corresponding hydrocarbons.

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