The 13C CP/MAS NMR spectrum of [(n-C3H7)4N][Cd(SCN)3], 1, indicates the presence of three non-equivalent thiocyanate ligands, in agreement with the results of a recent single-crystal X-ray diffraction study. Examination of the 13C MAS line shapes allows direct measurement of the indirect spin-spin c
Carbon-13 spin diffusion in the determination of intermolecular structure in solids
β Scribed by P.Mark Henrichs; Max Linder
- Book ID
- 103191172
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 256 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0022-2364
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Relaxation calculations for rapidly spinning samples show that spin-lattice relaxation time (T 1Z ) anisotropy varies with the angle between the rotor spinning axis and the external field. When the rate of molecular motion is in the extreme narrowing limit, the measurement of T 1Z anisotropies for t
One- and two-dimensional 13C exchange nuclear magnetic resonance experiments under magic-angle spinning (MAS) can provide detailed information on slow segmental reorientations and chemical exchange in organic solids, including polymers and proteins. However, observations of dynamics on the time scal