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Carbon-13 nuclear magnetic resonance study of the bromo derivatives of 5α-cholestan-3-one and cholest-4-en-3-one

✍ Scribed by Johannes Römer; Dieter Scheller; Gisbert Grossmann

Publisher: John Wiley and Sons
Year: 1987
Tongue: English
Weight: 516 KB
Volume: 25
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260250210

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✦ Synopsis

The 13C N M R spectra of nineteen bromo derivatives of 5ru-cholestan-3-one, cholest4-en-3-one and cholest-5-en-3one have been recorded. The substituent effects are analysed and examined with respect to additivity. The more interesting ys,,, and ylmti effects are considered in detail.

KEY WORDS 13C NMR Bromo derivatives of 5a-cholestan-3-one and cholest-4-en-3-one Substituent effects in Tables 1 and2. The tables do not include the chemical shifts of the side-chain carbons, for which the following

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