✦ LIBER ✦
Carbon-13 nuclear magnetic resonance spectra. XVI—lanthanide induced signal shifts of diastereotopic 13C nuclei as a probe for a conformational equilibrium
✍ Scribed by Helmut Duddeck; Volker Wiskamp
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 161 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The ^13^C NMR signals of the two methyl groups in 4‐hydroxy‐1‐isopropyl‐2‐oxaadamantane are anisochronous in the presence of Yb(fod)~3~. This is interpreted in terms of the different populations of three rotational conformers.