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Carbon-13 NMR study of enamines and enamino ketones. A direct observation of the conformation of the 2-methylcyclohexanone enamine tautomers

✍ Scribed by D. Tourwé; G. Van Binst; S. A. G. De Graaf; U. K. Pandit

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
704 KB
Volume
7
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The carbon‐13 spectra of a series of cyclohexanone, cyclopentanone and 2‐methylcyclohexanone enamines are reported. The influence of the amino component was studied in a series of enamino ketones. The spectra reflect the amount of p‐π overlap in the molecules and their conformation. Differences between 5‐and 6‐membered carbonyl components are evaluated.

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