## Abstract The ^13^C chemical shifts of 17 indazole derivatives are discussed as a function of substituent effects and the N‐1—H or N‐2—H structure of indazole. The presence in solution of the N‐1—H tautomer is confirmed.
Carbon-13 n.m.r. studies of substituted bisalkylamino-s-triazines in acidic media
✍ Scribed by C. K. Tseng; A. Mihailovski
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 179 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0749-1581
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The carbon‐13 n.m.r. spectra of six substituted bisalkylamino‐s‐triazines are reported. The site of protonation of 2‐methoxy‐s‐triazines is shown to be at N‐1 or N‐3. The effect of trifluoroacetic acid on 2‐chloro‐s‐triazines is also discussed.
📜 SIMILAR VOLUMES
## Abstract The ^13^C n.m.r. spectra of a variety of purines and 8‐azapurines have been studied in aqueous basic medium; the shifts were measured using dioxane as reference, and corrected to the TMS scale. The compounds studied include adenine, hypoxanthine, 6‐mercaptopurine, guanine, xanthine, 8‐a
## Abstract The carbon‐13 n.m.r. spectra of some 3‐substituted‐2‐cyclohexenones show very wide variations in chemical shift at C‐3 that correlate with Pauling electronegativity χ, even wider variations at C‐2 that correlate with the Taft resonance parameter σ~R~º and almost no variation at C‐1. The
## Abstract Carbon‐13 n.m.r. spectra of 3‐hydroxy‐4‐sulpho‐2‐naphthoic, 3‐hydroxy‐5‐sulpho‐2‐naphthoic, 3‐hydroxy‐7‐sulpho‐2‐naphthoic, 5‐sulphosalicylic, 3‐hydroxy‐5,7‐disulpho‐2‐naphthoic, 1‐hydroxy‐4,7‐disulpho‐2‐naphthoic, and 3,5‐disulphosalicylic acids were recorded with and without proton no
## Abstract ^13^C n.m.r. spectra are reported for 1,3‐indandione, phthalic anhydride, thiophthalic anhydride, and phthalimide in chloroform‐__d__ solution. The ^13^C chemical shifts have also been calculated by means of Pople's perturbation theory using CNDO/S wave functions; the agreement between
## Abstract ^13^C n.m.r. spectra are reported for 1,2‐indandione, coumarandione and thionaphthenequinone in CDCl~3~ solution and for isatin in dimethyl sulphoxide solution. The chemical shifts are assigned and discussed in connection with the influence of the heteroatom on the dicarbonyl group and