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Carbon-13 NMR studies. 73—carbon-13 spectra of several 10-methyl-trans-decalins. Further definition of the deshielding antiperiplanar γ effect

✍ Scribed by W. A. Ayer; L. M. Browne; S. Fung; J. B. Stothers

Publisher: John Wiley and Sons
Year: 1978
Tongue: English
Weight: 866 KB
Volume: 11
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270110205

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✦ Synopsis

Abstract

The ^13^C spectra of a series of 21 10‐methyl‐trans‐decalins have been recorded to explore in greater detail the deshielding antiperiplanar γ effects found earlier in a few of these derivatives. From the data for the series complete assignments for each compound were obtained, permitting an analysis of the shielding effects of the methyl and hydroxyl groups.

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Carbon-13 NMR Studies: 82. Carbon-13 spectra of several 10-methyl-cis-decalins. Conformational preferences of some cis-decalin derivatives

✍ L. M. Browne; R. E. Klinck; J. B. Stothers 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 885 KB

## Abstract The ^13^C spectra of a series of 21 __cis__‐decalins, 17 of which bear 10‐methyl substituents, have been recorded to examine geometrical and conformational effects on the ^13^C shieldings. Although the data for a few of the simpler examples have been reported, these compounds were exami