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Carbon-13 NMR spectra of adamantane carboxylic acids and diamantane mono- and di-carboxylic acids and esters

✍ Scribed by Milan Hájek; LuděK Vodička; Petr Trška; Vladimír Sklenář

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
257 KB
Volume
23
Category
Article
ISSN
0749-1581

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✦ Synopsis

Table 4. Predicted and observed" aryl carbon shieldings relative to benzene for the 4-substituted phenylsulphonyl moiety in cis-and trans-l-arylsulphonyl-2-~lcy~opropanes shielding (pprn) Compound cis trans No. C-1' C-2 and C-6' C-3' and C-5' C-4' C-1' C-2 and C 6 ' C-3' and C-5' C-4' Carbon-13 NMR Spectra of Adamantane Carboxylic Acids and Diamantane Mono-and Di-carboxylic Acids and Esters The 13C NMR chemical shifts of 17 adamantane and diamantane mono-and dicarboxylic acids and methyl esters have been measured in CDCI, and D,O. The assignment of the chemical shifts was verified using an additivity rule and the lanthanide shift technique.

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