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Carbon-13 magnetic resonance shifts in triscyclopentadienyl uranium(IV) chloride

✍ Scribed by Eiichi Fukushima; Samuel D. Larsen

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 339 KB
Volume: 44
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80511-8

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✦ Synopsis

Carbon-l 3 NMR shift of (CsH& UCI in THT: for 160 Z T r; 320 K consists of a Curie-Weiss part with a Weiss tempcnturc of 140 f 10 K and a temperature-independent part of i-59 ppm with respect to TMS. The contact shift is -309 C 120 ppm at 290 K and is larger than the pseudocontact shift by about a factor of two.

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