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Carbon-13 chemical shifts of monosubstituted cyclohexanes

✍ Scribed by T. Pehk; E. Lippmaa

Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
518 KB
Volume
3
Category
Article
ISSN
0749-1581

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✦ Synopsis

The carbon-13 chemical shifts of monosubstituted cyclohexane derivatives are compared with those of aliphatic compounds. The polar substituents exert a similar influence on the M-, Band y-carbons in both series of compounds. The 8-effect is shown to be characteristic mainly to the cyclic compounds, however. The appearance of a 8-effect is discussed as a possible consequence of electron delocalization in alicyclic molecules. A correlation of these &effects with inductive parameters of the substituents is presented.

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