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Carbolithiation of Vinyl Pyridines as a Route to 7-Azaindoles.

✍ Scribed by Bertrand Cottineau; Donal F. O'Shea

Publisher: John Wiley and Sons
Year: 2005
Weight: 30 KB
Volume: 36
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200527145

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## Abstract An efficient synthesis of enaminones **1a‐c** is reported. Compounds **1a‐c** reacted with diefhyl‐3‐amino‐2‐cyanopenten‐1,5‐dicarboxylate (**3**) to yield the benzonitriles **6**. On the other hand, the reaction of **la‐c** with 3‐amino‐2‐cyano‐2‐pentene dinitrile (**7**) afforded a mi