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Carbodiphosphoranes: The Chemistry of Divalent Carbon(0)

✍ Scribed by Ralf Tonner; Florian Öxler; Bernhard Neumüller; Wolfgang Petz; Gernot Frenking

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
33 KB
Volume
46
Category
Article
ISSN
0044-8249

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Divalent Carbon(0) Chemistry, Part 2: Pr
Divalent Carbon(0) Chemistry, Part 2: Protonation and Complexes with Main Group and Transition Metal Lewis Acids
✍ Ralf Tonner; Gernot Frenking 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 653 KB

## Abstract Quantum‐chemical calculations with DFT (BP86) and ab initio methods (MP2, SCS‐MP2) were carried out for protonated and diprotonated compounds N‐H^+^ and N‐(H^+^)~2~ and for the complexes N‐BH~3~, N‐(BH~3~)~2~, N‐CO~2~, N‐(CO~2~)~2~, N‐W(CO)~5~, N‐Ni(CO)~3~ and N‐Ni(CO)~2~ where N=C(PH~3