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Carboazidation of Chiral Allylsilanes: Experimental and Theoretical Investigations

✍ Scribed by Laurent Chabaud; Yannick Landais; Philippe Renaud; Frédéric Robert; Frédéric Castet; Marco Lucarini; Kurt Schenk

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
597 KB
Volume
14
Category
Article
ISSN
0947-6539

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## Abstract The thermodynamic and kinetic parameters for the reaction of 1‐methylphosphirane with dimethylphosphide (PMe), proceeding via attack at the ring phosphorus atom to give Me~2~P–PMe^−^ plus ethylene, were calculated at the G3(MP2)‐RAD(+) level. The rate constant for this mechanism (__k__