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Carbenic reactions of 4-diazo-4h-imidazole with benzene derivatives

✍ Scribed by T.J. Amick; H. Shechter

Book ID
104218246
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
273 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis

The electrophilic behavior of 4H-imidazolylidene is greatly modified by coordinating groups in benzene derivatives undergoing substitution. Carbenes (Y2C:) react with benzenes (C6H5Z) to give (1) bicyclo[4.l.O]heptadienes (i) which may convert to other bicyclo[4.l.O]heptadienes (;I), cycloheptatrienes (2) and their re-

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