Carbene rearrangements. 43. Carbenes in Constrained Systems. 2. First Carbene Reactions within Zeolites: Solid-State Photolysis of Adamantane-2-spiro-3'-diazirine

Carbenes in constrained systems, 3. Soli

Carbenes in constrained systems, 3. Solid-State photolysis of cycloheptane- and cyclooctanespirodiazirine within cyclodextrins and zeolites

✍ Kupfer, René ;Brinker, Udo H. 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 476 KB

## Abstract Inclusion complexes of cycloheptanespirodiazirine (1) and cyclooctanespirodiazirine (8) in α‐, β‐, and γ‐cyclodextrin, and faujasite type zeolites (NaX and NaY), have been prepared. The guest‐host complexes (1‐ and 8@CD and 1‐ and 8@zeolite) were irradiated with UV light in the solid st