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Carbene reactions, XX. Structural Aspects Responsible for the Thermal Extrusion of Carbenes from Norbornadienes

✍ Scribed by Hoffmann, Reinhard W. ;Barth, Wolfgang ;Schüttler, Reinhard ;Mayer, Bernhard

Publisher
Wiley (John Wiley & Sons)
Year
1986
Tongue
English
Weight
1009 KB
Volume
119
Category
Article
ISSN
0009-2940

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The pyrolysis of ethynylbenzene (1) in helium was studied in a tubular flow reactor at 10.7 mbar/103O0C and reaction times ranging from 5 to 30 ms. Reactive intermediates such as radicals and carbenes were scavenged with dimethyl disulfide (DMDS). Qualitative and quantitative analysis of the scaveng