Carbene-like reactions of stannous halides with dimethylacetylene dicarboxylate
✍ Scribed by P.G. Harrison
- Book ID
- 107768652
- Publisher
- Elsevier Science
- Year
- 1972
- Weight
- 97 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0020-1650
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📜 SIMILAR VOLUMES
## Abstract An efficient N‐heterocyclic carbene‐catalyzed oxidative esterification reaction of aldehydes with alkyl halides or alkyl 4‐methylbenzenesulfonate is reported. It was worth noting that (1) the configuration of alkyl halides or alkyl 4‐methylbenzenesulfonates was inverted completely, and
A Biginelli-type condensation is described using dialkyl acetone-1,3-dicarboxylates as active methylene compounds for the preparation of monastrol analogues. Unexpectedly, the reaction with salicylaldehyde formed two different products depending on the ester alkyl group. This product dichotomy was f