Carbene Complexes of Metalloporphyrins and Heme Proteins
β Scribed by Gerard Simonneaux; Paul Le Maux
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 49 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
For Abstract see ChemInform Abstract in Full Text.
π SIMILAR VOLUMES
The solution structure of polypeptides can now be achieved through NMR spectroscopy, as long as the molecular mass does not much exceed 40 000 Da [1][2][3][4][5]. The determination of the structure of heme proteins, however, requires the knowledge of the position of the iron and of the atoms of the
An overview of the use of classical mechanical molecular simulations of porphyrins, hydroporphyrins and heme proteins is given. The topics cover molecular mechanics calculations of structures and conformer energies of porphyrins, energies of barriers for interconversion between stable conformers, mo