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Carbene and Nitrene Rearrangements: A Theoretical Study of Cyclic Allenes and Carbenes, Carbodiimides, and Azirines

✍ Scribed by Kuhn, Arvid; Vosswinkel, Michael; Wentrup, Curt


Book ID
125429287
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
217 KB
Volume
67
Category
Article
ISSN
0022-3263

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The potential-energy surfaces for the abstraction reactions of carbenes with oxirane and thiirane have been characterized in detail by using density functional theory (B3LYP/6-31G\*), which include zero-point corrections. Six carbene species: dimethylcarbene, cyclobutylidene, cyclohexylidene, phenyl