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Carbanions from deprotonation of .alpha.-(phenylthio)alkaneboronic esters

โœ Scribed by Matteson, Donald S.; Arne, Karl


Book ID
126071977
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
249 KB
Volume
100
Category
Article
ISSN
0002-7863

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Preparation of ฮฑ-substituted S-phenylthi
โœ Mark Ashwell; Richard F.W. Jackson; Joanna M. Kirk ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 1021 KB

## 2-Nitro-2-phenylthio oniranes (3), prepared by nucleophilic epoxidation of I-nitro-I-phenyllhio alkenes (I), react with a v&y of heteroatomic nucleophiles to give a-substituted S-phenylthio esters (2). Of special note is the efficient reaction of 2-n&o-2-phenylthio oxiranes with boron trifruOride