Carbanion reactivity, kinetic and equilibrium studies of ?-adduct formation and elimination in the reactions of 4-nitrobenzofurazan derivatives with nitroalkane anions
โ Scribed by Asghar, Basim H. M.; Crampton, Michael R.
- Book ID
- 118743046
- Publisher
- Royal Society of Chemistry
- Year
- 2007
- Tongue
- English
- Weight
- 201 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1477-0520
- DOI
- 10.1039/b703154h
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Kinetic and equilibrium results are reported for the reactions of sulphite with the ethyl and phenyl ethers of 2,4,6-trinitrophenol and 2,4,6-trinitrothiophenol in 80/20 (v/v) water/DMSO. In each case 1:1 and 1:2 adducts are observed by reaction of sulphite at one or two unsubstituted ring positions
Reactions of morpholine in dimethyl sulphoxide at unsubstituted ring positions of 1,3,5-trinitrobenzene, and phenyl 2,4,64rinitrophenyl ether, yield anionic a-adducts via zwitterionic intermediates. Reactions at the 1- position of phenyl 2,4,64rinitrophenyl ether, phenyl 2,4-dinitronaphthyl ether, a