Carbanion-Induced Base-Catalyzed Synthesis of 1H-Isothiochromenes, Benzo[c]thiochromenes, Benzo[c]chromenes, and 1-Benzothiophenes through Ring-Transformation Reactions of 6-Aryl-2H-pyran-2-ones†
✍ Scribed by Ram, Vishnu Ji; Srivastava, P.; Saxena, Abhishek S.
- Book ID
- 111918023
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 125 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0022-3263
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An efficient and convenient synthesis of 2-(5-aryl-8-nitro-2,3-dihydroimidazo[1,2-a]pyridin-7(1H)-ylidene)acetonitriles (3) and 6-aryl-4-{2-[(E)-nitromethylidene]-1-imidazolidinyl}-2-oxo-2H-pyran-3-carbonitriles (4) through nucleophile induced ring transformation of suitably functionalized 2H-pyran-