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Carbanion and Radical Intermediacy in the Electrochemical Reduction of Benzyl Halides in Acetonitrile

โœ Scribed by Koch, Del A.

Book ID
121699443
Publisher
The Electrochemical Society
Year
1987
Tongue
English
Weight
747 KB
Volume
134
Category
Article
ISSN
0013-4651

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โœ James Y. Becker; Theodore A. Koch ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 276 KB

The electrochemical reduction of five conjugated and non-conjugated nitriles, CH3CH--CHCN (la, trans/cis = 62/38%); CH3CH2CH--CHCN (lb, cis); CH3CH~CHCH2CN (lc, trans), CH3CH~C(CH3)CN (ld) and CH2~CHCH(CH3)CN (le) have been investigated in acetonitrile, and of two derivatives, la and CHz--C(CH3)CN (