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Carbaborane-Substituted 1,2-Diphosphetanes

✍ Scribed by Anika Kreienbrink; Menyhárt B. Sárosi; Dr. Evgeny G. Rys; Dr. Peter Lönnecke; Prof. Dr. Evamarie Hey-Hawkins

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
292 KB
Volume
50
Category
Article
ISSN
0044-8249

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Di-1-propynyl-tetramethyldisilane (1) reacts with triorganoboranes R,B [R = Et (2a), CH2Ph (2b), Ph (2c), 2-thienyl (2d)], 9-ethyl-9-borabicyclo[3.3. llnonane (3), and diethyl(N-pyrroly1)borane (4) by twofold 1,l-organoboration to give selectively the respective organo-substituted 1,2-dihydro-1,2,5-