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Capture-ROMP-Release: Application to the Synthesis of Amines and Alkyl Hydrazines.

✍ Scribed by Shubasish Mukherjee; Kevin W. C. Poon; Daniel L. Flynn; Paul R. Hanson


Publisher
John Wiley and Sons
Year
2003
Weight
109 KB
Volume
34
Category
Article
ISSN
0931-7597

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Atropisomerism at C–N Bonds of Acyclic A
✍ Takashi Mino; Haruka Yamada; Shingo Komatsu; Mizuki Kasai; Masami Sakamoto; Tsut πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 278 KB

## Abstract Acyclic amines **1** were obtained by a nucleophilic aromatic substitution (S~N~Ar) reaction and __N__‐methylation followed by silane reduction. The optical resolution of C(aryl)–N(amine) bond atropisomers of amines **1** is described. We found that chiral acyclic amine **1a** can be re